High Quality Chinese Factory supply 3087-39-6 Tetra t-Butyl Titanate

  • Molecular Formula:C16H36O4Ti
  • Molecular Weight:340.339
  • Vapor Pressure:46mmHg at 25°C 
  • Refractive Index:n20/D 1.438  
  • Boiling Point:70oC (2 mmHg) ,84.6oC at 760 mmHg 
  • Flash Point:11.7oC 
  • PSA:36.92000 
  • Density:0.881 g/mL at 25 °C(lit.)  
  • LogP:5.06320 

Tetra-tert-butyl orthotitanate(Cas 3087-39-6) Usage

Flammability and Explosibility

Flammable

InChI:InChI=1/4C4H9O.Ti/c4*1-4(2,3)5;/h4*1-3H3;/q4*-1;+4

3087-39-6 Relevant articles

Atom-bridged intermediates in N- and P-atom transfer reactions

Johnson,Lee,Odom,Davis,Cummins

, p. 87 - 91 (2008/10/09)

Formal N-atom insertion into the metal m...

SYNTHESIS OF ALKYL ORTHOTITANATES IN TWO-PHASE SYSTEMS.

Yatluk,Suvorov

, p. 1678 - 1680 (2008/10/08)

The authors have carried out an investig...

3087-39-6 Process route

titanium tetrachloride
7550-45-0

titanium tetrachloride

<i>tert</i>-butyl alcohol
75-65-0

tert-butyl alcohol

titanium(IV) tert-butoxide
3087-39-6

titanium(IV) tert-butoxide

Conditions
Conditions Yield
With lithium; N,N-dimethyl-formamide; In hexane; alcohol added at the boil to a suspension of Li in hexane, stirred cooled, TiCl4 and HCON(CH3)2 added dropwise with stirring; upper layer separated, solvent removed, product distilled under vacuum;
84.6%
tris(tert-butyloxy)nitridomolybdenum
82209-31-2

tris(tert-butyloxy)nitridomolybdenum

tetrakis(dimethylamino)titanium
3275-24-9

tetrakis(dimethylamino)titanium

Mo(≡N)(NMe<sub>2</sub>)<sub>3</sub>
183559-62-8

Mo(≡N)(NMe2)3

titanium(IV) tert-butoxide
3087-39-6

titanium(IV) tert-butoxide

Conditions
Conditions Yield
In toluene; N2-atmosphere; equimolar amts., stirring for 3 h; crystn. (-35°C; two crops), collection (filtration), washing (pentane), drying (vac.); elem. anal.;
88.6%

3087-39-6 Upstream products

  • 3087-36-3
    3087-36-3

    titanium (IV) ethoxide

  • 75-65-0
    75-65-0

    tert-butyl alcohol

  • 7550-45-0
    7550-45-0

    titanium tetrachloride

  • 82209-31-2
    82209-31-2

    tris(tert-butyloxy)nitridomolybdenum

3087-39-6 Downstream products

  • 127936-80-5
    127936-80-5

    1-allyloxy-3-tert-butoxy-2-propanol

  • 152752-38-0
    152752-38-0

    2-hydroxy-3-allyloxypropyl 4-toluenesulfonate

  • 75567-13-4
    75567-13-4

    2-(tert-butoxy)-2-phenylethanol

  • 68938-62-5
    68938-62-5

    (RS)-3-phenoxy-1-(4-toluenesulfonyloxy)-2-propanol

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Key words:

Tetra t-Butyl Titanate

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Commodity Name:Tetra t-Butyl Titanate
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