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Tetra ethyl titanate
▲ CROSSLINKING: TET can be used to crosslink polymers or binders containing functional groups such as – OH or –COOH.
▲ COATINGS: Glass, metals, fillers and pigments can be treated with TET to increase surface hardness, promote adhesion, improve resistance to heat, chemicals, corrosion and scratches, add iridescence or coloring effects or enhance light reflection.
▲ TIO2 PIGMENT AND FILMS: Micro- or nano-scale TiO2 pigments can be formed from TET, which also can also be used to create polymeric TiO2 films on surfaces via pyrolytic or hydrolytic (e.g. sol-gel) processes. Total or partial hydrolysis of TET in sol-gel applications, typically in combination with other metal alkoxides, produces metal oxide systems for use as binders or coatings.
| Item | Specification | Results |
|---|---|---|
| Appearance | Light yellow liquid | Light yellow liquid |
| TiO 2 content(%) | 33.0-35.0 | 34.20 |
| Density(20/20℃) | 1.08-1.10 | 1.09 |
| Volatiles | 1.0% Max | 0.5% |
| Product Name | Tetra-ethyl titanate (TET) |
| CAS No. | 3087-36-3 |
| Content | TET:83.5-86.5% TIPT:13.5-16.5% |
| Molecular formula | Ti(OEt)4 |
| Molecular Weight | 228 |
| Flashpoint | 33-43℃ |
| Boiling point | 150-155℃ |
| Pour Point | -40℃ |
| Rafractive Index(25℃) | 1.490-1.510 |
| Packing | 200kgs/drum,1000kgs/IBC drum |
Chinese Manufacturer Supply Tetra ethyl titanate 3087-36-3 On Stock with Competitive Price
- Molecular Formula:C8H20O4Ti
- Molecular Weight:228.124
- Appearance/Colour:colourless liquid
- Vapor Pressure:57.26hPa at 19.6℃
- Melting Point:54 °C
- Refractive Index:n20/D 1.505(lit.)
- Boiling Point:150-152 °C10 mm Hg(lit.)
- Flash Point:84 °F
- PSA：36.92000
- Density:1.088 g/mL at 25 °C(lit.)
- LogP:1.94880
Titanium ethoxide(Cas 3087-36-3) Usage
|
Flammability and Explosibility |
Flammable |
|
Application |
Titanium(IV) ethoxide can be used:As an activator and dehydrating agent for by condensation of (S)-(+)-p-toluenesulfinamide with aldehydes and ketones to form sulfinimines.As a Ti4+ ion source to form complexes of titanium (IV) acrylate with methacrylic acid.As a catalyst to synthesize esters of sterically hindered alcohols via transesterification reactions. |
|
Materials Uses |
Titanium ethoxide is used widely as a precursor for the synthesis of Ti4+ ions titania nanoparticles by various techniques such as :in the sol-gel synthesis of free-standing ferroelectric lead zirconate titanate nanoparticlesspherical titania cores, produced either by hydrolysis of Ti(IV) ethoxide droplets in contact with water vapor orby preadsorption of the titanium alkoxides into/onto the clay mineral platelets and their subsequent hydrolysis and calcination. |
InChI:InChI=1/4C2H5O.Ti/c4*1-2-3;/h4*2H2,1H3;/q4*-1;
3087-36-3 Relevant articles
-
MacCorquodale,Adkins
, p. 1938 (1928)
-
-
Cullinane,Chard
, p. 710 (1949)
-
Alkoxy metal powder as well as preparation method and application thereof
-
Paragraph 0099-0100, (2019/12/02)
The invention relates to a preparation m...
SYNTHESIS OF ALKYL ORTHOTITANATES IN TWO-PHASE SYSTEMS.
Yatluk,Suvorov
, p. 1678 - 1680 (2008/10/08)
The authors have carried out an investig...
3087-36-3 Process route
-
- 917-58-8
potassium ethoxide
-
- 7550-45-0
titanium tetrachloride
-
- 3087-36-3
titanium (IV) ethoxide
| Conditions | Yield |
|---|---|
|
In hexane; at 60 ℃; for 5h; Inert atmosphere;
|
15.3 g |
-
- 64-17-5
ethanol
-
- 7550-45-0
titanium tetrachloride
-
- 3087-36-3
titanium (IV) ethoxide
| Conditions | Yield |
|---|---|
|
With NH4I-NH3; In tetrachloromethane; soln. of TiCl4 added to alcohol with cooling and stirring, soln. added to NH4I-NH3 with stirring and cooling at 0-15°C; organic layer separated, solvent removed, product distilled under vacuum;
|
84% |
|
With NH4NO3-NH3; In tetrachloromethane; soln. of TiCl4 added to alcohol with cooling and stirring, soln. added to NH4NO3-NH3 with stirring and cooling at 0-15°C; organic layer separated, solvent removed, product distilled under vacuum;
|
82% |
|
With formamide; In tetrachloromethane; byproducts: NH4Cl; soln. of TiCl4 added to alcohol with cooling and stirring, HCONH2 added, mixture boiled with stirring for 5-6 h, cooled; NH4Cl separated by filtration or HCONH2 added with stirring, product distilled under vacuum;
|
75% |
|
With NH4NCS-NH3; In tetrachloromethane; soln. of TiCl4 added to alcohol with cooling and stirring, soln. added to NH4NCS-NH3 with stirring and cooling at 0-15°C; organic layer separated, solvent removed, product distilled under vacuum;
|
22% |
|
In ethanol; not isolated;
|
3087-36-3 Upstream products
-
64-17-5
ethanol
-
141-52-6
sodium ethanolate
-
7550-45-0
titanium tetrachloride
-
917-58-8
potassium ethoxide
3087-36-3 Downstream products
-
992-92-7
titanium tetramethoxide
-
3087-39-6
titanium(IV) tert-butoxide
-
4092-07-3
5-<2,6,6-Trimethyl-cyclohexen-(2)-yl>-3-hydroxy-3-methyl-penten-(4)-saeure-aethylester
-
3007-97-4
ethyl 1-naphthoate
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